diff --git a/packages/react-native/src/private/webapis/structuredClone/__tests__/structuredClone-itest.js b/packages/react-native/src/private/webapis/structuredClone/__tests__/structuredClone-itest.js
index 402e055048d..93fb418d58a 100644
--- a/packages/react-native/src/private/webapis/structuredClone/__tests__/structuredClone-itest.js
+++ b/packages/react-native/src/private/webapis/structuredClone/__tests__/structuredClone-itest.js
@@ -62,8 +62,18 @@ describe('structuredClone', () => {
   });
 
   it('clones primitive value wrappers', () => {
+    const throwUnexpectedCoercion = () => {
+      throw new Error('Unexpected coercion');
+    };
+    const preventCoercion = (value: interface {}) => {
+      Object.defineProperty(value, Symbol.toPrimitive, {
+        value: throwUnexpectedCoercion,
+      });
+    };
+
     // eslint-disable-next-line no-new-wrappers
     const numberValue = new Number(1);
+    preventCoercion(numberValue);
     const numberClone = structuredClone(numberValue);
     expect(numberClone).not.toBe(numberValue);
     expect(numberClone).toBeInstanceOf(Number);
@@ -71,17 +81,18 @@ describe('structuredClone', () => {
 
     // eslint-disable-next-line no-new-wrappers
     const stringValue = new String('foo');
+    preventCoercion(stringValue);
     const stringClone = structuredClone(stringValue);
     expect(stringClone).not.toBe(stringValue);
     expect(stringClone).toBeInstanceOf(String);
     expect(stringClone.valueOf()).toBe('foo');
 
     // eslint-disable-next-line no-new-wrappers
-    const booleanValue = new Boolean(true);
+    const booleanValue = new Boolean(false);
     const booleanClone = structuredClone(booleanValue);
     expect(booleanClone).not.toBe(booleanValue);
     expect(booleanClone).toBeInstanceOf(Boolean);
-    expect(booleanClone.valueOf()).toBe(true);
+    expect(booleanClone.valueOf()).toBe(false);
   });
 
   it('throws with symbols, functions, WeakMap, WeakSet, Promise', () => {
@@ -200,6 +211,11 @@ describe('structuredClone', () => {
 
   it('clones dates', () => {
     const value = new Date('1993-06-11T14:30:45.123Z');
+    Object.defineProperty(value, Symbol.toPrimitive, {
+      value() {
+        throw new Error('Unexpected coercion');
+      },
+    });
     const clone = structuredClone(value);
     expect(clone).not.toBe(value);
     expect(clone).toBeInstanceOf(Date);
diff --git a/packages/react-native/src/private/webapis/structuredClone/structuredClone.js b/packages/react-native/src/private/webapis/structuredClone/structuredClone.js
index 89a7f90725b..dce16a83303 100644
--- a/packages/react-native/src/private/webapis/structuredClone/structuredClone.js
+++ b/packages/react-native/src/private/webapis/structuredClone/structuredClone.js
@@ -24,9 +24,15 @@ const VALID_ERROR_NAMES = new Set([
   'URIError',
 ]);
 
-const BASIC_CONSTRUCTORS = [Number, String, Boolean, Date];
-
 const ObjectPrototype = Object.prototype;
+// $FlowFixMe[method-unbinding] this is always called with an explicit receiver.
+const numberValueOf = Number.prototype.valueOf;
+// $FlowFixMe[method-unbinding] this is always called with an explicit receiver.
+const stringValueOf = String.prototype.valueOf;
+// $FlowFixMe[method-unbinding] this is always called with an explicit receiver.
+const booleanValueOf = Boolean.prototype.valueOf;
+// $FlowFixMe[method-unbinding] this is always called with an explicit receiver.
+const dateValueOf = Date.prototype.valueOf;
 
 // Technically the memory value should be a parameter in
 // `structuredCloneInternal` but as an optimization we can reuse the same map
@@ -95,13 +101,35 @@ function structuredCloneInternal<T>(value: T): T {
 
   // Handles complex types (typeof === 'object').
 
-  for (const Cls of BASIC_CONSTRUCTORS) {
-    if (value instanceof Cls) {
-      const result = new Cls(value);
-      memory.set(value, result);
-      // $FlowExpectedError[incompatible-type] we know result is T
-      return result;
-    }
+  if (value instanceof Number) {
+    // eslint-disable-next-line no-new-wrappers
+    const result = new Number(numberValueOf.call(value));
+    memory.set(value, result);
+    // $FlowExpectedError[incompatible-type] we know result is T
+    return result;
+  }
+
+  if (value instanceof String) {
+    // eslint-disable-next-line no-new-wrappers
+    const result = new String(stringValueOf.call(value));
+    memory.set(value, result);
+    // $FlowExpectedError[incompatible-type] we know result is T
+    return result;
+  }
+
+  if (value instanceof Boolean) {
+    // eslint-disable-next-line no-new-wrappers
+    const result = new Boolean(booleanValueOf.call(value));
+    memory.set(value, result);
+    // $FlowExpectedError[incompatible-type] we know result is T
+    return result;
+  }
+
+  if (value instanceof Date) {
+    const result = new Date(dateValueOf.call(value));
+    memory.set(value, result);
+    // $FlowExpectedError[incompatible-type] we know result is T
+    return result;
   }
 
   if (value instanceof Map) {